包明,男,毕业于东北大学,博士,现为大连理工大学精细化工国家重点实验室教授、博士生导师。

主要研究金属有机化学、有机合成化学、应用化学

人物经历

教育经历

工作经历

1989.7—1997.10,硕士毕业后留校工作,历任助教、讲师。

2001.4—2002.10,日本产业技术综合研究所特别研究员。

2002.11—2004.12,日本学术振兴会(JSPS)特别研究员。

2005.1—现在,大连理工大学精细化工国家重点实验室教授、博士生导师。

主要成就

科研成就

研究领域

金属有机化学、有机合成化学、应用化学。

论文

(2000年以来的论文,SCI检索)

1. Zhang, S.; Wang, Y.; Feng, X.; Bao, M., Palladium-Catalyzed Amination of Chloromethylnaphthalene and Chloromethylanthracene Derivatives with Various Amines. Journal of the American Chemical Society 2012, 134 (12), 5492–5495.

2. Dai, Y.; Feng, X.; Wang, B.; He, R.; Bao, M., Preparation and application of air-stable P,N-bidentate ligands for the selective synthesis of δ-lactone via the catalyzed telomerization of 1,3-butadiene with dioxide. Journal of Organometallic 化学 2012, 696, (26), 4309-4314.

3. Lu, S.; Jin, T.; Bao, M.; Yamamoto, Y., Catalyzed Hydroalkylation of Fullerene with Active Alkyl Bromides: Selective Synthesis of Monoalkylated Fullerenes. Journal of the American Chemical Society 2011, 133, (32), 12842-12848.

4. Lu, S.; Jin, T.; Kwon, E.; Bao, M.; Yamamoto, Y., Highly Efficient Cu(OAc)2-Catalyzed Dimerization of Monofunctionalized Hydrofullerenes Leading to Single-Bonded Fullerene Dimers. Angewandte Chemie International Edition 2011, 51, (3), 802-806.

5. Dai, Y.; Feng, X.; Liu, H.; Jiang, H.; Bao, M., Synthesis of 2-Naphthols via Carbonylative Stille Coupling Reaction of 2-Bromobenzyl Bromides with Tributylallylstannane Followed by the Heck Reaction. The Journal of Organic Chemistry 2011, 76, (24), 10068-10077.

6. Xu, Z.; Yu, X.; Feng, X.; Bao, M., Propargylamine Synthesis by Catalyzed Oxidative 耦合 of Alkynes and Tertiary Amine N-Oxides. The Journal of Organic 化学 2011, 76, (16), 6901-6905.

7. Peng, B.; Zhang, S.; Yu, X.; Feng, X.; Bao, M., Nucleophilic Dearomatization of Chloromethyl Naphthalene Derivatives via η3-Benzylpalladium Intermediates: A New Strategy for 催化 Dearomatization. Organic Letters 2011, 13, (19), 5402-5405.

8. Feng, X.; Zhao, Z.; Yang, F.; Jin, T.; Ma, Y.; Bao, M., 1,3-Diynes synthesis by homo-coupling of terminal alkynes using a Pd(PPh3)4/氧化银 simple catalyst system. Journal of Organometallic Chemistry 2011, 696, (7), 1479-1482.

9. Zhou, X.-Y.; Wang, D.-S.; Bao, M.; Zhou, Y.-G., Palladium-catalyzed asymmetric hydrogenation of simple ketones activated by Br?nsted acids. Tetrahedron Letters 2011, 52, (22), 2826-2829.

10. Zhou, X.-Y.; Bao, M.; Zhou, Y.-G., Palladium-Catalyzed Asymmetric Hydrogenation of Simple Ketimines Using a Br?nsted Acid as Activator. Advanced Synthesis \u0026 Catalysis 2011, 353, (1), 84-88.

11. Yang, F.; Jin, T.; Bao, M.; Yamamoto, Y., Facile synthesis of 3,4-dihalofurans via electrophilic iodocyclization. Chemical Communications 2011, 47, (15), 4541-4543.

12. Yang, F.; Jin, T.; Bao, M.; Yamamoto, Y., Facile synthesis of diiodinated dihydronaphthalenes and naphthalenes via mediated electrophilic cyclization. Chemical Communications 2011, 47, (13), 4013-4015.

13. Feng, X. J.; Yan, M.; Zhang, X.; Bao, M., Preparation and application of SBA-15-supported palladium catalyst for Heck reaction in supercritical carbon dioxide. Chinese Chemical Letters 2011, 22, (6), 643-646.

14. Yang, F.; Jin, T.; Bao, M.; Yamamoto, Y., Facile synthesis of 3,4-diiododihydrothiophenes via electrophilic iodocyclization. Tetrahedron Letters 2011, 52, (8), 936-938.

15. Dai, Y.; Liu, H.; Feng, X.; Bao, M., Preparation and Application of New P, N-Ligands for Palladium-Catalyzed C-N Bond Coupling Reaction. Chinese Journal of Catalysis 2011, 32, (10), 1617-1623.

16. Yu, X.; Ma, Y.; Zhao, Z.; Xu, Z.; Bao, M., Cross-Coupling Reaction of 苄型 Halides with Allyltributylstannane Catalyzed by Cu(OTf)(2). Chinese Journal of Catalysis 2011, 32, (3), 472-476.

17. Peng, B.; Feng, X.; Zhang, X.; Ji, L.; Bao, M., Regioselective control using a catalyst switch in the reaction of diarylmethyl chlorides with allyltributylstannane. Tetrahedron 2010, 66, (32), 6013-6018.

18. Liu, Y.; Feng, X. J.; Bao, D. C.; Li, K. X.; Bao, M., Preparation of microcapsule-supported palladium catalyst using SPG (Shirasu Porous Glass) emulsification technique. Chinese Chemical Letters 2010, 21, (8), 979-982.

19. Du, X.; Feng, X. J.; Liu, Y.; He, R.; Bao, M., Suzuki reaction of bromoallenes with arylboronic acids using an air-stable palladium complex Pd(Ph2PCH2CO2)2 as a precatalyst. Chinese Chemical Letters 2010, 21, (6), 641-645.

20. Liu, Y.; Feng, X.; Bao, D.; Li, K.; Bao, M., A new method for the preparation of microcapsule-supported palladium catalyst for Suzuki coupling reaction. Journal of Molecular Catalysis A: Chemical 2010, 323, (1-2), 16-22.

21. Peng, B.; Feng, X.; Zhang, X.; Zhang, S.; Bao, M., Propargylic and Allenic Carbocycle Synthesis through Palladium-Catalyzed Dearomatization Reaction. The Journal of Organic Chemistry 2010, 75, (8), 2619-2627.

22. Lu, S.; Jin, T.; Bao, M.; Yamamoto, Y., PalladiumCatalyzed Three-Component [3 + 2] Cycloaddition of Propargyl Trifluoroacetates, Ethylidene Malononitriles, and Allyltributylstannane. Organic Letters 2010, 12, (4), 864-866.

23. Feng, X.; Yan, M.; Zhang, T.; Liu, Y.; Bao, M., Preparation and application of SBA-15-supported palladium catalyst for Suzuki reaction in supercritical dioxide. Green 化学 2010, 12, (10), 1758-1766.

24. Zhou, L.; Du, X.; He, R.; Ci, Z.-H.; Bao, M. Nickel Salt-catalyzed Addition Reaction of Arylboronic Acids to Aromatic Aldehydes, Tetrahedron Lett. 2009, 50, 406–408.

25. Lu, S.-R.; Xu, Z.-W.; Bao, M.; Yamamoto, Y. Carbocycle Synthesis through Facile and Efficient Palladium-Catalyzed Allylative Dearomatization of Naphthyl- and Phenanthryl-Allyl Chlorides, Angew. Chem. Int. Ed. 2008, 47, 4366-4369.

26. Zhou, L.; Miao,Q.-Q.; He, R.; Feng, X.-J.; Bao, M. Ni-catalyzed Cross-Coupling Reaction of Aryl Chlorides with Arylboronic Acids in IPA without Using a Reducing 化学试剂, Tetrahedron Lett., 2007, 48, 7899-7902.

27. Du, X.; Dai, Y.; He, R.; Lu, S.-R.; Bao, M. A New Application of N- Halosuccinimide/PPh3 for the Halogenation of Propargyl Alcohols to Haloallenes, Synth. Commun. 2009, 39, (21), 3940-3949.

28. Zhou, L.; Feng, X.-J.; He, R.; Bao, M. X-ray Structure of trans-Chloro(1-naphthyl) bis(triphenylphosphane)(II) and its Application for Catalytic Dehalogenation of Aryl Chlorides, J. Coord. Chem. 2009, 62, (17), 2824-2831.

29. Bao, M.; Hayashi, T.; Shimada, S. Cationic Organobismuth Complex with 5,6,7,12-Tetrahydrodibenz[c,f][1,5] azabismocine Framework and Its Coordination Complexes with Neutral Molecules, Organometallics, 2007, 26, 1816-1822.

30. Bao, M.; Shimizu, M.; Shimada, S; Inoue, J.; Konakahara, T. Reactions of N-Sulfenyl-1,2-benzisothiazolin-3-ones with Nucleophiles, Tetrahedron, 2004, 60, 11359-11366.

31. Bao, M.; Hayashi, T.; Shimada, S. Synthesis and Structural Characterization of a Cationic Trinuclear Organobismuth Complex with an Unprecedented Coordination Mode of Hydrotris(2-mercaptoimidazolyl)borate Ligands, Dalton Transactions, 2004, 2055-2056.

32. Bao, M.; Hatanaka, Y.; Shimada, S. The First Synthesis and X-ray Structure of [1.1]Silaferrocenophane Containing Pentacoordinate Moieties, Chem. Lett., 2004, 33 (5), 520-521.

33. Bao, M.; Shimizu, M. N-Trifluoroacetyl Arenesulfenamides, Efficient Precursors for Synthesis of Unsymmetrical Disulfides and Sulfenamides, Tetrahedron, 2003, 59, 9655-9659.

34. Bao, M.; Shimizu, M.; Shimada, S.; Tanaka, M. Efficient Synthesis of N-Acylarenesulfenamides by Acylation of Arenesulfenamides, Tetrahedron, 2003, 59, 303-309.

35. Bao, M.; Nakamura, H.; Inoue, A.; Yamamoto, Y. Nucleophilic Allylation-Heterocyclization via Bis-π-allylpalladium Complexes: Synthesis of Five- and Six-Membered Heterocycles, Chem. Lett., 2002, 2, 158-159.

36. Nakamura, H.; Bao, M.; Yamamoto, Y. The Fate of Bis(η3-allyl) Complexes in the Coexistence of Aldehydes (or Imines) and Allylic Chlorides. Stille Coupling versus Allylation of Aldehydes (or Imines), Angew. Chem. Int. Ed., 2001, 40, 3208-3210.

37. Bao, M.; Nakamura, H.; YAMAMOTO, Y. Facile Allylative Dearomatization Catalyzed by Palladium, J. Am. Chem. Soc., 2001, 123, 759-760.

38.Bao, M.; Nakamura, H.; Yamamoto, Y. Preparation and Application of Polymer-Supported Chiral π-allylpalladium Catalyst for the Allylation of Imines, Tetrahedron Lett., 2000, 41, 131-134.

39. 陆仕荣,彭勃,包明*,芳香族化合物的脱芳构化反应研究进展,化学进展, 2007, 19, 1529-1536.

40. 张涛,冯秀娟,王春霞,包明*,超临界二氧化碳介质中钯催化的一些交叉偶联反应的研究,有机化学,2007, 27, 1463-1472.

鉴定成果

吉林省科委项目“有机锡新农药的合成和生物活性的研究”,登记号: 96128-1,1996年10月,第一完成人。

专利成果

获日本专利成果6项,申请中国专利5项。

教学成就

讲授课程

本科课程:有机化学,有机化学实验。

硕士研究生课程:有机合成化学,有机合成化学实验。

博士研究生课程:工业催化过程化学与研究。

指导硕、博士生研究方向

有机合成方法学

(1)钯催化脱芳构化反应及其在生物活性物质、功能材料合成中的应用。

(2)兰尼镍在氯代芳烃的偶联反应、羰基化合物加成反应及芳香卤代烃脱卤反应中的活用。

(3)不对称催化反应—将手性催化剂应用于本组发现的新有机反应

(4)均相催化反应的复相化研究—微胶囊膜内负载过渡金属催化剂,形成微催化反应环境。

绿色化学

(1)二氧化碳的催化活化及资源化利用—合成医药中间体、功能材料。

(2)超临界二氧化碳介质中有机合成反应的研究。

(3)环境友好型蒸汽机车精细化学品的合成研究。

社会活动

大连理工大学“分子的高效活化转化与新物质创造”科研创新团队成员、教育部“光转化功能分子设计合成及应用”创新团队成员、抚顺精细化工应用技术研究院科技专家、中国化学会会员、中国化学会催化学会均相催化专业委员会委员。

获得荣誉

参考资料

大连理工大学主页平台管理系统 包明--中文主页--首页.大连理工大学.2021-03-20